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段文增老师简介

duanwenzeng@lcu.edu.cn

段文增 副教授

E-mail：duanwenzeng@lcu.edu.cn

duanwenzeng@163.com

山东省聊城市东昌府区聊城大学东校区新匍京娱乐场湖南路1号

出生日期：1981.01.17

籍贯：山东聊城

科研方向：有机合成化学；药物化学；手性荧光探针合成；荧光识别手性小分子

讲授课程：有机化学，精细单元反应，有机专论实验，有机化学实验。

教育经历:

2000.01-2004.06 聊城大学 学士；

2004.09-2007.06 山东大学 硕士；

2009.09-2013.06 山东大学 博士。

2019.09-2020.07 美国弗吉尼亚大学 访问学者

科研项目

(1) 国家自然科学基金委员会，青年项目，21801108，新型双功能过渡金属配合物的设计、合 成及碳氢键官能团化研究，2019/01-2021/12，26万元，在研，参与。

(2) 山东省自然科学基金委员会，面上项目，ZR2017MB052，基于面手性[2.2]环仿的新型BODIP Y类荧光分子的构筑及发光性质的研究，2017/08-2020/06，13万元，在研，主持。

(3) 山东省自然科学基金委员会，联合专项项目，ZR2012BL08，具有中心手性和面手性的卡宾 催化剂的合成及其催化性能的研究，2013/01-2015/12，4万元，已结题、主持。

论著一览：

 1- Solvatochromism, acidochromism and aggregation-induced emission of propeller-shaped spiroborates

Kang Li, Jichun Cui, Zeren Yang, Yanmin Huo, Wenzeng Duan*, Shuwen Gong*, Zhipeng Liu*.

Dalton Transactions, 2018, 47, 15002-15008.

 2- An NHC-CuCl functionalized metal-organic framework for catalyzing β-boration of α,β-unsaturated carbonyl compounds

Qingxia Yao*, Xiufang Lu, Kaili Liu, Chao Ma, Jie Su, Cong Lin, Dacheng Li, Jianmin Dou, Junliang Sun*, Wenzeng Duan*.

Dalton Transactions, 2019, 48,5144-5148.

 3- AIE-active boron complexes based on benzothiazole–hydrazone chelates

Wenzeng Duan(Qingsong Liu), Yanmin Huo, Jichun Cui, Shuwen Gong*, Zhipeng Liu*.

Organic & Biomolecular Chemistry, 2018, 16, 4977-4987. (Cover paper)

 4- NHC-Pd complex based on 1,3-bis (4-ethoxycarbonylphenyl) imidazolium chloride: synthesis, structure and catalytic activity in the synthesis of axially chiral benzophenone hydrazone

Wenzeng Duan*, Zhaofeng Sun, Yanmin Huo, Yanke Liu, Guangqing Wu, Ruifeng Wang , Shuang Wu, Qingxia Yao*, Shuwen Gong*.

Applied Organometallic Chemistry, 2018, e4444, 1-6.

 5- Design and synthesis of novel rhodamine-based chemodosimeters derived from [2.2]paracyclophane and their application in detection of Hg2+ ion

Wenzeng Duan, Yinfeng Han, Qingsong Liu, Jichun Cui, Shuwen Gong*, Yudao Ma*, Changli Zhang*, Zhaofeng Sun

Tetrahedron Letter, 2017, 58, 271-278.

 6- Synthesis of novel planar chiral Ag and Rh N-heterocyclic carbine complexes derived from [2.2]paracyclophane and their application in ultrasound assisted asymmetric arylation of aldehydes.

Wenzeng Duan, Yudao Ma*, Fuyan He, Lei Zhao, Jianqiang Chen, Chun Song*.

Tetrahedron: Asymmetry., 2013, 24, 241-248. (Cited by Synfacts).

 7- Synthesis of new alkoxy/sulfonate-substituted carbene precursors derived from [2.2]paracyclophane and their application in the asymmetric arylation of aldehydes.

Wenzeng Duan, Yudao Ma*, Bo Qu, Lei Zhao, Jianqiang Chen, Chun Song.

Tetrahedron: Asymmetry, 2012, 23, 1369-1375.

 8- Crystal structure studies towards the synthesis and applications of N-heterocyclic carbene–metal complexes derived from [2.2]paracyclophane

Wenzeng Duan, Yudao Ma,* Yanmin Huo, Qingxia Yao

Australian Journal of Chemistry, 2015, 68, 1472-1478.

 9- Design and synthesis of planar chiral heterocyclic carbene precursors derived from [2.2]paracyclophane

Wenzeng Duan, Yudao Ma*, Houqi Xia, Xueying Liu, Qingshuang Ma, Junshan Sun

The Journal of Organic Chemistry. 2008, 73(11), 4330-4333.

 10- Synthesis, Crystal Structure and Theoretical Calculation of [2-(2, 6-dioxacyclohexyl), 5-methoxylphenols]2

Wenzeng Duan, Shuai Feng, Bin Sun

Chinese Journal Structure Chemistry. 2009, 28(10), 1290-1295.

 11- Bis(2,2’-bipyridyl-κ2N,N’)(nitrato-κ2O,O’)(trifluoroacetato-κO)-cadmium(II)

Wenzeng Duan*, Junshan Sun, Yudao Ma, Rentao Wu

Acta Crystallographica Section E. 2009, 65, m635.

 12- 4-Amino-12-methylsulfonyloxy-[2.2]paracyclophane

Xiangchao Meng, Wenzeng Duan*, Yinfeng Han

Acta Crystallographica Section E. 2014, 70, o18.

 13- Determination of Vitamin D2 and Vitamin D3 in Dairy Products by HPLC-APCI (+)-MS/MS

Yanmin Huo*, Jun Wang, Wenzeng Duan*, Xia Xue, Yanli Wang, Wenjiang Yu

Chinese Journal of Instrumental Analysis. 2016, 35(3), 327-331.

 14- Axially chiral 1,4-dihydropyridine derivatives: aggregation-induced emission in exciplexes and application as viscosity probes

Zeren Yang, Yanmin Huo, Yanke Liu, Guifen Du, Wenhao Zhang, Lijie Zhou,

Lihui Zhan, Xuerui Ren, Wenzeng Duan* and Shuwen Gong*

RSC Advances. 2019, 9, 32219-32225.

 15- [2.2] Paracyclophane-based carbene–copper catalyst tuned by transannular electronic effects for asymmetric boration

Jianqiang Chen, Wenzeng Duan, Xhen Chen, Manyuan Ma, Chun Song*, Yudao Ma*

RSC Advances. 2016, 6(79), 75144-75151.

 16- Asymmetric β‑Boration of α,β-Unsaturated N‑Acyloxazolidinones by [2.2]Paracyclophane-Based Bifunctional Catalyst

Lei Zhao, Yudao Ma*, Wenzeng Duan, Fuyan He, Jianqiang Chen, Chun Song

Organic Letters, 2012, 14(22), 5780-5783.

 17- Synthesis of Cyclophanes with Planar and Helical Chirality

Xiao Liu, Yudao Ma*, Wenzeng Duan, Fuyan He, Lei Zhao, Chun Song

The Journal of Organic Chemistry. 2011, 76(6), 1953-1956.

 18- Synthesis of [2.2]paracyclophane-based bidentate oxazoline–carbene ligands for the asymmetric 1,2-silylation of N-tosylaldimines

Xichao Wang, ZhenChen, Wenzeng Duan, Chun Song*, Yudao Ma*

Tetrahedron : Asymmetry, 2017, 28(6), 783-790.

 19- Synthesis and application of a dual chiral [2.2]paracyclophane-based N-heterocyclic carbene in enantioselective β-boration of acyclic enones

Lei Wang, ZhenChen, Manyuan Ma, Wenzeng Duan, Chun Song*, Yudao Ma*

Organic & Biomolecular Chemistry, 2015, 13, 10691-10698.

 20- Planar chiral imidazolium salts based on [2.2]paracyclophane in the asymmetric rhodium-catalyzed 1,2-addition of arylboronic acids to aldehydes

Qingshuang Ma, Yudao Ma*, Xiao Liu, Wenzeng Duan, Bo Qu, Chun Song

Tetrahedron: Asymmetry, 2010, 21(3), 292-298.

 21- An isophorone-based far-red emitting ratiometric fluorescent probe for selective sensing and imaging of polysulfides

Liming Zhao, Qian Sun, Chuanzhi Sun, Changli Zhang,* Wenzeng Duan, Shuwen Gong* and Zhipeng Liu*

Journal of Materials Chemistry B, 2018, 6, 7015-7020.

 22- Coexistence of self- and interpenetration in two (3,6)-connected porous coordination polymers

Qingxia Yao, Yerong Fan, Zhan Wang, Wenzeng Duan, Suna Wang, Yunwu Li, Dacheng Li,* Qingfu Zhang, Yuchang Du and Jianmin Dou*

CrystEngComm, 2016, 18, 8574-8577.

 23- Metal-free catalytic enantioselective silylation of aromatic aldehydes in water

Yuwen Huo, Panpan Shen, WenzengDuan, Zhen Chen, Chun Song*, Yudao Ma*

Chinese Chemical Letters. 2018, 29(9), 1359−1362.

专利：

(1) 段文增，孙君善，程远志，周子腾，李震，韩银锋，候现明，马世营。

基于[2.2] 环 仿 类 罗 丹 明 Hg2+ 荧 光 探 针 材 料 及 其 制 备 方 法 ，CN105400506A ， 发明专利，2016.03.16。

(2) 段文增，李康，龚树文，霍艳敏。

面手性环仿 BODIPY 的制备及固体荧光应用，CN109735131A，发明专利，2019.05.10

参加会议情况:

 Yanmin Huo, Wenzeng Duan*, et al. The synthesis and crystal structure studies of zinc coordination compounds derived from [2.2]paracyclophanyl carboxylic acid.

CCSThe 9th National Organic Chemistry Conference , 28th-31th July, 2015, Changchun, China.

 Wenzeng Duan*, et al. The synthesis of rhodamine-based fluorescent probe derived from [2.2]paracyclophane.

CCSThe 9th National Organic Chemistry Conference , 28th-31th July, 2015, Changchun, China.

 Kang Li, Wenzeng Duan*, et al. The design and synthesis of chiral AIE-active spiroborates

The 1st Symposium on Aggregation-induced Emission (AIE) of Chinese, 26th-29th September, 2018, Xi’an, China.

所获奖励：

 泰安市嘉奖, 2012.06.

 聊城大学第五届青年教师讲课比赛一等奖 2017.12

 聊城大学第四届青年教师讲课比赛三等奖 2017.01.